Some types of domain extensions have restrictions for who can register them, requiring a local presence (address), or citizenship, or proof of professional affiliation requirements.
Where possible we try to offer these extensions, but for some of them the restrictions are so extensive that few interested parties would be able to meet them.
And sometimes the paperwork required to provide the necessary documentation is just too cumbersome, manual, or slow to be worth it for our customers.
Beyond that, generally for the extensions we don't carry, demand is very low, so the level of bureaucracy required to register them just isn't worth it for how many of those domains would be registered as a result.
We are always working on adding new top-level domains to iwantmyname, and you should also check out domai.nr to search for domains that we currently don't support.